Was just geeking around the interweb when I stumbled across this picture, which claims that for some constructed approximation of "consonance" (I think it's an algorythm), intervals played by two sawtooth waves sound more "musical" than that played by two square waves. In effect they have different "sweet spots" for consonant sounding ratios of freqs. I've flicked through "On The Sensations of Tone" and saw a similar chart in there for intervals created with tuning forks (almost sine-based tones).
I understand that odd harmonics and even harmonics are different, square waves are about the most "unnatural" sound you can get (consisting of nothing but discontinuities and pauses, being the "voice of electronics" etc) but at the end of the day if you set up an interval on a synth with two saw waves and then switch to squares, the interval doesn't really change for me. (or rather, it's degree of consonance doesn't seem to change).
But I haven't delved into psychoacoustics that much (at all, really). To me it's more about aesthetics than anything measurable. I like square waves because they remind me of cheap electronics, and the love humans put into them. But then I also like saw waves for their raspiness.
To me the square wave (or odd harmonic series, if you want to forget about phase) sounds more "voluminous" than a saw. It suggests space resonating. That's why it makes a killer bass. The saw wave suggests something else, it's unidirectional, more focussed. On an oscilloscope, saw waves tend to glide over eachother, whereas squares crash into eachother creating abrupt changes. Perhaps this is why history has granted us the "supersaw" and not the "supersquare".
If a square wave isn't tuned into the same intervallic consonances as a saw wave, is there some different set of intervals or maybe even a tuning system which is more suited to square waves?
Please note, this is just some jumbled thoughts which I thought might make an interesting discussion, not a thesis or anything fancy like that
And obviously, square vs saw is NOT a dichotomy in any meaningful way (other than it's a choice you have to make on analog-style synths) but this thought leads more into how we percieve odd harmonics versus a mixture of odd and even, and how timbre and harmony interact.