I'll start with a few:
Modulator Out
Found in the I/O group, this deceivingly simple module seems to be a huge part of Grid workflow. You may have noticed that only a few standard parameters for each module have regular patch cables - what if you want to modulate the Fold on the Triangle oscillator with the output of a separate Sine oscillator for example? To achieve this, route your desired modulation signal into a 'Modulator Out' device. You can now use the standard Bitwig modulation arrow on the Modulator Out to send that signal to any parameter you want in the grid.

Some components have the usual Bitwig modulation output arrow by default so you don't need to hook the output up to a Modulator Out to access their output signal as a wireless modulation source - LFOs and Envelopes for example.

Modulating other devices and VSTs from modulation signals within the grid
Using the 'Modulator Out' device mentioned above, you can actually send modulation outside of the grid itself into the Pre FX and Post FX slots of the main Poly/FX Grid device. You could use an FX grid to create an absurdly complex modulation system then drop whatever 3rd party VST you want into the FX slot and modulate it directly from your grid creation.

Feedback
You can achieve rudimentary feedback by routing any signal to the "Modulator Out" device, then adding a "Value" device (in the Level group), then modulating the Value device by the Modulator Out, then routing the output of the Value back into whichever input port you couldn't originally send a feedback loop to. Here's an example with a sine oscillator modulating its own phase:

I assume there is some latency inherent in the feedback loop (one buffer probably) but haven't tested yet.
Modulating envelope curves
I noticed that envelopes have a curve control (a single dot in the middle of an envelope stage) that can be controlled via the mouse but not modulated directly in the envelope component GUI itself. However, if you use a wireless modulation source (either from an LFO/Envelope or by creating one via the Modulation Out device), then select the envelope you want to modulate, you will see the envelope curvature for each stage shown in the inspector panel as an available modulation target.



