I will paste Olicash response to a similar question on discord:
"It determines the level from which the envelope starts when a voice is stolen (this includes playing a second note when one is already playing if mono enabled). Default settings are that the amp env (env 1) starts from whatever level it was at in the previous voice before it was stolen, as this helps reduce clicks. Envs 2-4 start from whatever the start level is set to (default 0). Note the amp env (1) does not have an editable start value, it always starts from 0."
